Published 1972 | Version v1
Journal article Metadata-only

Synthesis and investigation of deuterated allyl methyl ether in the mass spectrometer

Creators

  • 1. Marburg Univ. (F.R. Germany). Arbeitsgruppen fuer Organische Chemie

Description

3-Methoxy-propen-3-d1 (4), 3-Methoxy-propen-2-d1 (6), and 3-Methoxy-propen-1-d1 (8) were synthesized. The cleavage of the C-2–C-3 bond under electron impact occurs after the redistribution of deuterium in the molecular ion, decreasing in the order 4 ≃ 6 > 8.

Abstract (German)

3‐Methoxy‐propen‐3‐d 1 ( 4 ), 3‐Methoxy‐propen‐2‐d 1 ( 6 ) und 3‐Methoxy‐propen‐1‐d 1 ( 8 ) wurden dargestellt. Der Bruch der C‐2–C‐3‐Bindung unter Elektronenstoß erfolgt nach Umverteilung des Deuteriums in Molekül‐Ion, die in der Reihenfolge 4 ≃ 6 > 8 abnimmt.

Additional details

Additional titles

Original title (German)
Synthese und Massenspektrometrie deuterierter Methyl-allyl-aether

Identifiers

DOI
10.1002/cber.19721050317;

Publishing Information

Journal Title
Chemische Berichte
Journal Volume
105
Journal Issue
3
Series
Chem. Ber.
Journal Page Range
859-862
ISSN
0009-2940

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
3030860
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CHEMICAL ANALYSIS; DEUTERIUM; DISTRIBUTION; ETHERS; LABELLED COMPOUNDS; MASS SPECTROSCOPY; STEREOCHEMISTRY; SYNTHESIS
Descriptors DEC
HYDROGEN ISOTOPES; ISOTOPES; LIGHT NUCLEI; NUCLEI; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; SPECTROSCOPY; STABLE ISOTOPES

Optional Information

Notes
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