Published August 1994 | Version v1
Journal article Metadata-only

Synthesis and structure of ferricenium pertechnetate

Creators

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Kosmicheskikh Issledovanij
  • 2. AN SSSR, Moscow (Russian Federation). Inst. Fizicheskoj Khimii

Description

Ferricenium pertechnetate has been prepared by the reaction of exchange of hydroxonium cations in aqueous solution of technetium acid for ferricenium cations. The compound has been prepared both in polycrystal form and in the form of monocrystal used for X-ray diffraction analysis: a = 8.967(3), c 12.464 (7) A, sp.gr. P3121; Z = 3, d(calcd) = 2.00 g/cm3. The compound is built of isolated cations of ferricenium and pertechnetate - ions. Tc-O distance equals 1.69 A. 5 refs.; 1 fig.; 2 tabs

Additional details

Additional titles

Original title (Russian)
Синтез и структура пертехнетата феррициния

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
20
Journal Issue
8-9
Journal Page Range
p. 671-673.
ISSN
0132-344X
CODEN
KOKHDC

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
27010111
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CHEMICAL PREPARATION; CRYSTAL LATTICES; DENSITY; FERROCENE; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MONOCRYSTALS; PERTECHNETATES; POLYCRYSTALS; SPACE GROUPS
Descriptors DEC
COMPLEXES; CRYSTAL STRUCTURE; CRYSTALS; DIENES; DISTANCE; HYDROCARBONS; IRON COMPLEXES; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; POLYENES; SYMMETRY GROUPS; SYNTHESIS; TECHNETIUM COMPOUNDS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS