Published November 2003 | Version v1
Journal article Metadata-only

Interaction of mixed-metal oxides with supercritical isopropanol

Creators

  • 1. RAN, Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova, Moscow (Russian Federation)

Description

Interaction between mixed-metal (M=Cd, Te, Mo, W, V, Bi, Pb) oxides and supercritical isopropanol was studied. It was shown that the following reactions are possible: reduction of a mixed-metal oxide with the formation of an eutectic alloy of two metal components, reduction of the formation of an intermetallide, selective reduction of an oxide component with the formation of a metal and an oxide of another component, and change in the oxygen stoichiometry of the oxide (extraction of oxygen from single crystals

Abstract (Russian)

Исследовано взаимодействие сложных оксидов металлов (M=Cd, Te, Mo, W, V, Bi, Pb) с суперкритическим изопропанолом. Показана возможность протекания следующих реакций: восстановления сложного оксида с образованием эвтектического сплава двух металлических компонентов; восстановления сложного оксида с образованием интерметаллида; селективного восстановления одного из компонентов сложного оксида с образованием металла и оксида второго компонента; изменения кислородной стехиометрии (экстракция кислорода из монокристаллов) оксидов

Additional details

Additional titles

Original title (Russian)
Взаимодействие сложных оксидов с суперкритическим изопропанолом

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
48
Journal Issue
11
Journal Page Range
p. 1765-1768
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36089443
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; BISMUTH OXIDES; CADMIUM OXIDES; CHEMICAL COMPOSITION; CHEMICAL REACTIONS; LEAD OXIDES; MOLYBDENUM OXIDES; PHASE STUDIES; PROPANOLS; SUPERCRITICAL STATE; TELLURIUM OXIDES; TUNGSTEN OXIDES; VANADIUM OXIDES
Descriptors DEC
ALCOHOLS; BISMUTH COMPOUNDS; CADMIUM COMPOUNDS; CHALCOGENIDES; HYDROXY COMPOUNDS; LEAD COMPOUNDS; MOLYBDENUM COMPOUNDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; REFRACTORY METAL COMPOUNDS; SPECTRA; TELLURIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS; VANADIUM COMPOUNDS

Optional Information

Notes
13 refs., 2 figs., 1 tab.