Published September 15, 1987 | Version v1
Journal article Metadata-only

Structure refinement of skutterudite-type cobalt triantimonide, CoSb3

Creators

  • 1. Siegen Univ. (Gesamthochschule) (Germany, F.R.). Lab. fuer Anorganische Chemie

Description

CoSb3, Mr=424.2, cubic, Imanti 3, a=9.0385(3) A [9.0775(6) A; two experiments with Cl2 and I2, respectively, as transport agents], V=738.40(7) [748.0(2)] A3, Z=8, Dx=7.63 (7.5B) Mg m-3, Mo Kα, λ=0.71073 A, μ=26.04 (25.71) mm-1, F(000)=1440, T=293 K, R=0.028 (0.031) for 418 (408) reflections. The structure of skutterudites with trigonally distorted CoSb6 octahedra {Co-Sb 2.5287(3) [2.5382(4)] A} and rectangular arrangement of the Sb atoms {Sb-Sb 2.8540(6) [2.8799(8)] and 2.9760(6) [2.9836(9)] A} is confirmed and refined. (orig.)

Additional details

Publishing Information

Journal Title
Acta Crystallogr., Sect. C
Journal Volume
43
Journal Issue
9
Series
Acta Crystallogr., Sect. C.
Journal Page Range
1678-1679
ISSN
0108-2701
CODEN
ACSCE

INIS

Country of Publication
Denmark
Country of Input or Organization
Denmark
INIS RN
19037974
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ANTIMONY ALLOYS; BOND ANGLE; COBALT ALLOYS; CRYSTAL STRUCTURE; CUBIC LATTICES; EXPERIMENTAL DATA; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MEDIUM TEMPERATURE; MONOCRYSTALS; X-RAY DIFFRACTION
Descriptors DEC
ALLOYS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTALS; DATA; DIFFRACTION; DISTANCE; INFORMATION; NUMERICAL DATA; SCATTERING