Published 2013 | Version v1
Journal article Metadata-only

Tungsten oxychloride compounds containing [W6O6Cl12]n- (n = 2, 3) clusters

Creators

  • 1. Institut fuer Anorganische Chemie, Abteilung fuer Festkoerperchemie und Theoretische Anorganische Chemie, Universitaet Tuebingen (Germany)

Description

Three tungsten oxychloride clusters containing the nearly D3d symmetric [(W6O6iCl6i)Cl6a]n- (n = 2, 3) core were prepared from the cluster acid (H5O2)2[W6O6Cl12].4H2O and structurally characterized by single-crystal X-ray diffraction. The copper compound [Cu(H2O)4][W6O6Cl12].12H2O releases water molecules to yield [Cu(H2O)6][W6O6Cl12]. Both compounds are represented as diamagnetic clusters, having 14 electrons in W-W bonding states. Magnetic measurements on the calcium compound [Ca(H2O)7]2[W6O6Cl12]Cl revealed a paramagnetic cluster having 15 valence electrons. (Copyright copyright 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/zaac.201300326

Additional details

Identifiers

DOI
10.1002/zaac.201300326;

Publishing Information

Journal Title
Zeitschrift fuer Anorganische und Allgemeine Chemie (1950)
Journal Volume
639
Journal Issue
14
Journal Page Range
p. 2637-2642
ISSN
0044-2313
CODEN
ZAACAB

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48044318
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CALCIUM COMPOUNDS; COPPER COMPOUNDS; CRYSTAL STRUCTURE; MAGNETIC PROPERTIES; MONOCRYSTALS; OXYCHLORIDES; TUNGSTEN COMPOUNDS; X-RAY DIFFRACTION
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; CHLORINE COMPOUNDS; COHERENT SCATTERING; CRYSTALS; DIFFRACTION; HALOGEN COMPOUNDS; OXYGEN COMPOUNDS; OXYHALIDES; PHYSICAL PROPERTIES; REFRACTORY METAL COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
With 7 figs., 2 tabs., 19 refs.