Published 1975 | Version v1
Journal article Metadata-only

Pulse radiolytic investigation of the SO2 radical ion

Creators

  • 1. Kungliga Tekniska Hoegskolan, Stockholm (Sweden). Institutionen foer Kaernkemi

Description

Aqueous solutions of sulphur dioxide in the presence of 1M formic acid/formate ion in the pH range 2-6 were pulse irradiated. The data presented indicate that radical SO2-. is formed by the charge-transfer reaction CO2-. + SO2→SO2-. + CO2 with k=/7.6+-1/x108 s-1.SO2-. recombine to form S2O42- with rate constant 2k=/2.2+-0.3/x109 M-1s-1 /at μ approximately 1/. The radiation source was a 7 MeV microtron. Beam current and pulse length were in the range /10-100/mA and /0.5-4/ μs respectively. The investigation was carried out in the pH-range from 2 to 6 and all solutions with pH>3.5 were saturated with N2O. (F.Gy.)

Additional details

Publishing Information

Journal Title
Radiochem. Radioanal. Lett.
Journal Volume
22
Journal Issue
1
Series
Radiochem. Radioanal. Lett.
Journal Page Range
33-40

INIS

Country of Publication
Hungary
Country of Input or Organization
Hungary
INIS RN
7239694
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CHARGE TRANSPORT; CHEMICAL REACTION KINETICS; CONTROLLED ATMOSPHERES; ELECTRON BEAMS; MEV RANGE 01-10; MILLI AMP BEAM CURRENTS; PH VALUE; PULSED IRRADIATION; RADICALS; RADIOLYSIS; SULFUR OXIDES
Descriptors DEC
BEAM CURRENTS; BEAMS; CHALCOGENIDES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CURRENTS; DECOMPOSITION; DISPERSIONS; ENERGY RANGE; HOMOGENEOUS MIXTURES; IRRADIATION; KINETICS; LEPTON BEAMS; MEV RANGE; MIXTURES; OXIDES; OXYGEN COMPOUNDS; PARTICLE BEAMS; RADIATION EFFECTS; REACTION KINETICS; SOLUTIONS; SULFUR COMPOUNDS

Optional Information

Notes
4 figs.; 10 refs.