Published April 1975 | Version v1
Journal article Metadata-only

Hydrogen isotope effect on radical addition reaction of sodium hydrogensulfite to allyl alcohol

Creators

  • 1. Japan Atomic Energy Research Inst., Takasaki, Gunma. Takasaki Radiation Chemistry Research Establishment

Description

The radical addition reaction of sodium hydrogensulfite to allyl alcohol in D2O solution was investigated. The hydrogen isotope effect was found to be 4.11. This effect is attributed to the hydrogen atom abstraction of HOCH2C HCH2SO3-( , radical) radical ion from hydrogensulfite ion. (auth.)

Additional details

Identifiers

DOI
10.1246/cl.1975.367;

Publishing Information

Journal Title
Chemistry Letters
Journal Volume
4
Journal Issue
4
Series
Chem. Lett. (Tokyo).
Journal Page Range
367-370
ISSN
0366-7022

INIS

Country of Publication
Japan
Country of Input or Organization
Japan
INIS RN
7259694
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ALCOHOLS; ALKENES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; DEUTERIUM; GAMMA RADIATION; HEAVY WATER; HYDROGEN COMPOUNDS; IRRADIATION; ISOTOPE EFFECTS; RADICALS; SODIUM COMPOUNDS; SULFITES
Descriptors DEC
ALKALI METAL COMPOUNDS; ELECTROMAGNETIC RADIATION; HYDROCARBONS; HYDROGEN ISOTOPES; HYDROXY COMPOUNDS; IONIZING RADIATIONS; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; STABLE ISOTOPES; SULFUR COMPOUNDS; WATER

Optional Information

Notes
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