Published October 10, 1986
| Version v1
Journal article
Synthesis of 1-alkylthio-3-allylthio-1-propenes by the reaction of dialllyl disulfide with allyl halides in the alkali-metal hydroxide-DMSO superbasic system
Creators
- 1. Irkutsk Institute of Organic Chemistry, USSR
Description
The reaction of diallyl disulfide with alkyl halides in the alkali-metal hydroxide-DMSO superbasic system leads to the formation of 1-alkylthio-3-allylthio-1-propenes and 1,3-di(alkylthio)propenes. The effects of the structure of the alkyl halides, the nature of the alkali-metal cations, the halogen, and the reaction conditions on the yield and ratio of the products were investigated
Additional details
Publishing Information
- Journal Title
- J. Org. Chem. USSR (Engl. Transl.)
- Journal Volume
- 22
- Journal Issue
- 5
- Series
- J. Org. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 856-861
- ISSN
- 0022-3271
- CODEN
- JOCYA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19007654
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ACTIVATION ENERGY; ALKENES; CARBON 13; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CHEMICAL SHIFT; COMPARATIVE EVALUATIONS; COUPLING CONSTANTS; DEUTERIUM COMPOUNDS; DISULFIDES; DMSO; HYPERFINE STRUCTURE; IONIZATION; ISOMERIZATION; ISOMERS; J-J COUPLING; LITHIUM HYDROXIDES; MASS SPECTRA; METHYL IODIDE; NMR SPECTRA; ORGANIC BROMINE COMPOUNDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC IODINE COMPOUNDS; POTASSIUM HYDROXIDES; SODIUM HYDROXIDES; SOLUBILITY; STRUCTURAL CHEMICAL ANALYSIS; SYNTHESIS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CARBON ISOTOPES; CHEMICAL REACTIONS; COUPLING; ENERGY; EVALUATION; EVEN-ODD NUCLEI; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROXIDES; INTERMEDIATE COUPLING; ISOTOPES; KINETICS; LIGHT NUCLEI; LITHIUM COMPOUNDS; NUCLEI; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; POTASSIUM COMPOUNDS; REACTION KINETICS; SODIUM COMPOUNDS; SPECTRA; STABLE ISOTOPES; SULFOXIDES
Optional Information
- Notes
- Translated from Zh. Org. Khim.; 22: No.5, 957-964(May 1986).