PρT measurements and derived properties of liquid 1-alkanols
- 1. Department of Chemistry, University of Burgos, 09001 Burgos (Spain)
- 2. Chemical Engineering Department, Qatar University, Doha (Qatar)
Description
Highlights: ► The PρT behaviour of 1-alkanols from ethanol to 1-undecanol is studied. ► Vibrating tube densimeter was used up to 60 MPa and 358.15 K. ► Thermophysical properties were analysed as a function of pressure, temperature and chain length. ► The available literature on 1-alkanols was reviewed and compared with the new reported results. - Abstract: The density of compressed liquid (C2 to C11) 1-alkanols was measured with a vibration tube densimeter over the temperature range from (278.15 to 358.15) K and pressures up to 60 MPa, with an uncertainty of ±0.0012 g · cm−3. Density values were correlated with pressure and temperature by the TRIDEN 10-parameter equation. Isothermal compressibility, isobaric thermal expansivity and internal pressure were calculated from the experimental results. The influence of the carbon-chain lengths over the thermophysical properties obtained was studied.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2011.10.023Additional details
Identifiers
- DOI
- 10.1016/j.jct.2011.10.023;
- PII
- S0021-9614(11)00383-1;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 47
- Journal Page Range
- p. 241-259
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 43082021
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALCOHOLS; COMPRESSIBILITY; DENSIMETERS; DENSITY; EQUATIONS; ETHANOL; LIQUIDS; PRESSURE DEPENDENCE; PRESSURE RANGE MEGA PA 10-100; TEMPERATURE RANGE 0273-0400 K
- Descriptors DEC
- ALCOHOLS; FLUIDS; HYDROXY COMPOUNDS; MEASURING INSTRUMENTS; MECHANICAL PROPERTIES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; PRESSURE RANGE; PRESSURE RANGE MEGA PA; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.