Visualization and dimensional scaling for some three-body problems in atomic and molecular quantum mechanics
- 1. Department of Mathematics and Institute for Quantum Studies, Texas A and M University, College Station, Texas 77843 (United States)
- 2. Department of Mathematical Sciences, University of Nevada, Las Vegas, Las Vegas, Nevada 89154-4020 (United States)
- 3. Laboratoire J.-L. Lions, Universite Pierre et Marie Curie, Paris Cedex 05 (France)
- 4. Department of Mathematics, University of Houston, Houston, Texas 77004 (United States)
Description
Three-body problems in atomic and molecular quantum mechanics, comprising one electron-two nuclei and two electron-one nucleus, are studied from their Schroedinger-Born-Oppenheimer models. The following are main topics of interest in this paper: (1) review of foundational mathematical properties of the multiparticle Schroedinger operator, (2) visualization of H2+ (hydrogen molecular ion)-like and He (helium)-like molecular and atomic states, and (3) spectrum of He obtained by the large-dimension scaling limit. The authors begin with topic (1) for the tutorial purpose and devote topics (2) and (3) to new contributions of the analytical, numerical, and visualization nature. Relevant heuristics, graphics, proofs, and calculations are presented
Additional details
Identifiers
- DOI
- 10.1063/1.2937002;
Publishing Information
- Journal Title
- Journal of Mathematical Physics
- Journal Volume
- 49
- Journal Issue
- 6
- Journal Page Range
- p. 062102-062102.57
- ISSN
- 0022-2488
- CODEN
- JMAPAQ
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39110406
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- BORN-OPPENHEIMER APPROXIMATION; ELECTRONS; HELIUM IONS; HYDROGEN IONS 2 PLUS; QUANTUM MECHANICS; SCHROEDINGER EQUATION; THREE-BODY PROBLEM
- Descriptors DEC
- APPROXIMATIONS; CALCULATION METHODS; CATIONS; CHARGED PARTICLES; DIFFERENTIAL EQUATIONS; ELEMENTARY PARTICLES; EQUATIONS; FERMIONS; HYDROGEN IONS; IONS; LEPTONS; MANY-BODY PROBLEM; MECHANICS; MOLECULAR IONS; PARTIAL DIFFERENTIAL EQUATIONS; WAVE EQUATIONS
Optional Information
- Notes
- (c) 2008 American Institute of Physics