Published December 1992
| Version v1
Journal article
Fixation and reduction of molecular nitrogen by [WH4(PC2H5Ph2)4] and [WH4(PCH3Ph2)4] in a γ-radiation field
- 1. Silesian Univ., Katowice (Poland). Inst. of Chemistry
Description
Hydride complexes of W(IV) with dpep (diphenylethylphosphine) and dpmp (diphenylmethylphosphine) were irradiated in tetrahydrofuran + cyclohexane (1:1) solutions, satured with N2+H2(1:3). Radiation yields of hydrazine, ammonia and amines were evaluated. The mechanism of reduction of molecular nitrogen is discussed. (author) 18 refs.; 3 figs.; 2 tabs
Additional details
Publishing Information
- Journal Title
- Journal of Radioanalytical and Nuclear Chemistry
- Journal Volume
- 163
- Journal Issue
- 2
- Journal Page Range
- p. 325-333.
- ISSN
- 0236-5731
- CODEN
- JRNCDM
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 24068798
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION YIELD; CYCLOHEXANE; HYDRAZINE; HYDRIDES; NITROGEN FIXATION; PHOSPHINES; RADIATION DOSES; REDUCTION; TETRAHYDROFURAN; TUNGSTEN COMPLEXES
- Descriptors DEC
- ALKANES; CHEMICAL REACTIONS; COMPLEXES; CYCLOALKANES; FURANS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; HYDROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; RADIATION EFFECTS; TRANSITION ELEMENT COMPLEXES; YIELDS