Published December 2004 | Version v1
Journal article Metadata-only

X-ray diffraction of [UO2SO4{NH2CON(CH3)2}2]

Creators

  • 1. Samarskij Gosudarstvennyj Univ., Samara (Russian Federation)
  • 2. RAN, Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova, Moscow (Russian Federation)

Description

Single crystals of [UO2SO4{NH2CON(CH3)2}2] (1) were prepared and studied by X-ray diffraction. The compound crystallizes in monoclinic system, space group P21/n, Z=8, a=14.496, b=8.712, c=24.069 A, β=103.76 Deg. The main structural units in the crystals of 1 are chains linked into a three-dimensional framework by a system of N-H...O hydrogen bonds. The crystal-chemical formula of the complex is AT11M21 (A=UN22+)

Abstract (Russian)

Проведены синтез и рентгеноструктурный анализ монокристаллов [UO2SO4{NH2CON(CH3)2}2] (1). Соединение кристаллизуется в моноклинной сингонии, пр. гр. P21/n, Z=8, a=14.496, b=8.712, c=24.069 A, β=103.76 град. Основные структурные единицы кристалла 1 - цепи, объединенные в трехмерный каркас системой водородных связей N-H...O. Кристаллохимическая формула комплекса AT11M21 (A=UN22+)

Additional details

Additional titles

Original title (Russian)
Рентгеноструктурное исследование [UO

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
49
Journal Issue
12
Journal Page Range
p. 2074-2079
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36094764
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CARBONIC ACID DERIVATIVES; CHEMICAL BONDS; CHEMICAL PREPARATION; LATTICE PARAMETERS; MONOCLINIC LATTICES; MONOCRYSTALS; ORGANIC NITROGEN COMPOUNDS; SULFATES; URANYL COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIMENSIONS; LENGTH; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; SULFUR COMPOUNDS; SYNTHESIS; URANIUM COMPLEXES

Optional Information

Notes
9 refs., 4 tabs.