Published September 2007 | Version v1
Journal article

Local moments, exchange interactions, and magnetic order in Mn-doped LaFe2Si2 alloys

  • 1. Faculty of Mathematics and Physics, Department of Condensed Matter Physics, Charles University, Ke Karlovu 5, 12116 Prague 2 (Czech Republic) and Institute of Physics of Materials, Academy of Sciences of the Czech Republic, Zizkova 22, 61662 Brno (Czech Republic)
  • 2. Faculty of Mathematics and Physics, Department of Condensed Matter Physics, Charles University, Ke Karlovu 5, 12116 Prague 2 (Czech Republic)
  • 3. Faculty of Natural Sciences, Department of Inorganic Chemistry, Charles University, Albertov 2030, 12840 Prague 2 (Czech Republic)

Description

Formation of local magnetic moments in the intermetallic compound LaFe2Si2 due to doping by a few at% of Mn has been investigated by theoretical and experimental tools. While a number of low-temperature experiments prove appearance of non-zero magnetic moments due to the Mn doping, the measured 57Fe Moessbauer spectra rule out sizable local moments of Fe atoms. This conclusion is in agreement with results of first-principles electronic structure calculations that yield non-vanishing moments only on Mn atoms. The calculated Mn-Mn exchange interactions are of both signs which indicate a magnetically frustrated ground state, probably with a spin-glass-like arrangement of the Mn moments

Additional details

Identifiers

DOI
10.1016/j.jmmm.2007.04.026;
PII
S0304-8853(07)00647-6;

Publishing Information

Journal Title
Journal of Magnetism and Magnetic Materials
Journal Volume
316
Journal Issue
2
Journal Page Range
p. e403-e406
ISSN
0304-8853
CODEN
JMMMDC

Conference

Title
Joint European magnetic symposia
Dates
26-30 Jun 2006
Place
San Sebastian (Spain)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
39033057
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
DENSITY FUNCTIONAL METHOD; DOPED MATERIALS; ELECTRONIC STRUCTURE; EXCHANGE INTERACTIONS; GROUND STATES; INTERMETALLIC COMPOUNDS; IRON ALLOYS; LANTHANUM ALLOYS; MAGNETIC MOMENTS; MOESSBAUER EFFECT; SILICON ALLOYS; SPIN GLASS STATE
Descriptors DEC
ALLOYS; CALCULATION METHODS; ENERGY LEVELS; INTERACTIONS; MATERIALS; RARE EARTH ALLOYS; TRANSITION ELEMENT ALLOYS; VARIATIONAL METHODS

Optional Information

Copyright
Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.