Published 1979 | Version v1
Journal article Metadata-only

Schiff base complexes of rhenium(IV) and rhenium(V)

Creators

  • 1. Imperial Coll. of Science and Technology, London (UK). Dept. of Chemistry

Description

The interaction of various Schiff bases, LH2, with trichloro-oxobis(triphenylphosphine)rhenium(V), tetrachlorobis(triphenylphosphine)ruthenium(IV), and other rhenium complexes has given rise to complexes of the following types: (a) Re2sup(V)O3L2 that have a linear O=Re-O-Re=O system with quadridentate ligands on each rhenium; (b) Resup(V)OClL that appear to be octahedral with trans O=Re-Cl groups; (c) Resup(IV)Cl2L that are octahedral with trans chlorines; (d) complexes that have neutral Schiff bases, LH2 bound to the metal. (author)

Additional details

Publishing Information

Journal Title
J. Chem. Soc. (London), Dalton Trans.
Journal Issue
no.3
Series
J. Chem. Soc. (London), Dalton Trans.
ISSN
0300-9246

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
10460504
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
CHEMICAL ANALYSIS; CHEMICAL PREPARATION; CHEMICAL REACTIONS; EXPERIMENTAL DATA; INFRARED SPECTRA; ISOLATED VALUES; LIGANDS; MOLECULAR STRUCTURE; ORGANIC PHOSPHORUS COMPOUNDS; OXYCHLORIDES; PHOSPHINES; RAMAN SPECTRA; RHENIUM CHLORIDES; RHENIUM COMPLEXES; RHENIUM COMPOUNDS; RHENIUM OXIDES; SCHIFF BASES
Descriptors DEC
CHALCOGENIDES; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; DATA; DATA FORMS; HALIDES; HALOGEN COMPOUNDS; IMINES; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS