Published July 1997 | Version v1
Journal article Metadata-only

Electrochemical behaviour of oxygen-containing molybdenum(6) ions in molten NaCl-2CsCl mixture

Creators

  • 1. Inst. vysokotemperaturnoj ehlektrokhimii UrO RAN, Ekaterinburg (Russian Federation)

Description

Chemical and electrochemical behaviour of oxygen-containing molybdenum(6) ions at 923 K in the NaCl-2CsCl melt depending on the gas-phase composition over the melt and the container material for the salt bath is studied through the voltamperic method. Kinetic parameters of the process of the MoO22+ complex ions discharge up to MoO2, transfer and diffusion coefficient, heterogenous constants of the charge transfer velocity are determined

Additional details

Additional titles

Original title (Russian)
Электрохимическое поведение кислородсодержащих ионов молибдена(6) в расплавленной cмеси NaCl-2CsCl

Publishing Information

Journal Title
Rasplavy
Journal Issue
no.4
Journal Page Range
p. 68-73
ISSN
0235-0106
CODEN
RASPEM

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
30019662
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AIR; CESIUM CHLORIDES; CHEMICAL REACTION KINETICS; CHLORINE; DIFFUSION; ELECTROCHEMISTRY; MOLTEN SALTS; MOLYBDENUM COMPLEXES; OXYCHLORIDES; REDUCTION; SODIUM CHLORIDES; TEMPERATURE RANGE 0400-1000 K
Descriptors DEC
ALKALI METAL COMPOUNDS; CESIUM COMPOUNDS; CHEMICAL REACTIONS; CHEMISTRY; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; ELEMENTS; FLUIDS; GASES; HALIDES; HALOGEN COMPOUNDS; HALOGENS; KINETICS; NONMETALS; OXYGEN COMPOUNDS; OXYHALIDES; REACTION KINETICS; SALTS; SODIUM COMPOUNDS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
22 refs., 4 figs.