Published May 2004 | Version v1
Journal article

Apparent molar volumes and apparent molar heat capacities of aqueous nickel(II) nitrate, copper(II) nitrate, and zinc(II) nitrate at temperatures from (278.15 to 393.15) K at the pressure 0.35 MPa

Description

Apparent molar volumes Vphi and apparent molar heat capacities Cp,phi were determined for aqueous solutions of nickel(II) nitrate, copper(II) nitrate, and zinc(II) nitrate at molalities m=(0.01 to 0.5) mol · kg-1, and at the pressure p=0.35 MPa. Solution densities obtained using a vibrating-tube densimeter at T=(278.15 to 368.15) K were used to calculate Vphi values. Heat capacity measurements obtained with a twin fixed-cell, differential-output, power-compensating, temperature-scanning calorimeter at T=(278.15 to 393.15) K were used to calculate values of Cp,phi. Our results were then fitted to functions of m and T and compared to literature values

Additional details

Identifiers

DOI
10.1016/j.jct.2004.02.008;
PII
S0021961404000424;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
36
Journal Issue
5
Journal Page Range
p. 437-446
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.