Published May 2004
| Version v1
Journal article
Apparent molar volumes and apparent molar heat capacities of aqueous nickel(II) nitrate, copper(II) nitrate, and zinc(II) nitrate at temperatures from (278.15 to 393.15) K at the pressure 0.35 MPa
Description
Apparent molar volumes Vphi and apparent molar heat capacities Cp,phi were determined for aqueous solutions of nickel(II) nitrate, copper(II) nitrate, and zinc(II) nitrate at molalities m=(0.01 to 0.5) mol · kg-1, and at the pressure p=0.35 MPa. Solution densities obtained using a vibrating-tube densimeter at T=(278.15 to 368.15) K were used to calculate Vphi values. Heat capacity measurements obtained with a twin fixed-cell, differential-output, power-compensating, temperature-scanning calorimeter at T=(278.15 to 393.15) K were used to calculate values of Cp,phi. Our results were then fitted to functions of m and T and compared to literature values
Additional details
Identifiers
- DOI
- 10.1016/j.jct.2004.02.008;
- PII
- S0021961404000424;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 36
- Journal Issue
- 5
- Journal Page Range
- p. 437-446
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 35070812
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- APPARENT MOLAL VOLUME; AQUEOUS SOLUTIONS; CALORIMETERS; COPPER NITRATES; DENSIMETERS; DENSITY; NICKEL NITRATES; PRESSURE RANGE KILO PA; SPECIFIC HEAT; TEMPERATURE RANGE 0273-0400 K; ZINC NITRATES
- Descriptors DEC
- COPPER COMPOUNDS; DISPERSIONS; HOMOGENEOUS MIXTURES; MEASURING INSTRUMENTS; MIXTURES; NICKEL COMPOUNDS; NITRATES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; PRESSURE RANGE; SOLUTIONS; TEMPERATURE RANGE; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; ZINC COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.