Published March 1981
| Version v1
Journal article
Photo- and radiation-induced alcoholysis and substitution of p-dicyanobenzene in 2-propanol
- 1. Jochi Univ., Tokyo (Japan). Faculty of Science and Technology
Description
The irradiation of p-dicyanobenzene with 254 nm light in 2-propanol causes the alcoholysis of CN group to give isopropyl p-cyanobenzimidate. The UV-irradiation in the presence of acetone or γ-irradiation brings about the substitution of cyano group by the hydroxyalkyl group derived from the alcohol. The substitution occurs via the electron transfer from hydroxyalkyl radicals or electrons followed, by the attack of hydroxyalkyl radicals. (author)
Additional details
Publishing Information
- Journal Title
- Chem. Lett. (Tokyo)
- Journal Volume
- 1981
- Journal Issue
- 3
- Series
- Chem. Lett. (Tokyo).
- Journal Page Range
- 303-306
- ISSN
- 0366-7022
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 13674344
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AROMATICS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; CYANIDES; ELECTRON TRANSFER; G VALUE; GAMMA RADIATION; IRRADIATION; NITRILES; PHOTOLYSIS; PROPANOLS; SOLVATED ELECTRONS; ULTRAVIOLET RADIATION
- Descriptors DEC
- ALCOHOLS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ELECTRONS; ELEMENTARY PARTICLES; FERMIONS; HYDROXY COMPOUNDS; IONIZING RADIATIONS; KINETICS; LEPTONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS