Published 1988 | Version v1
Journal article

Conventional vs gauge invariant quantum transition probabilities in simple systems

  • 1. Pisa Univ. (Italy). Dipt. di Chimica e Chimica Industriale
  • 2. Consiglio Nazionale delle Ricerche, Pisa (Italy). Ist. di Chimica Quantistica ed Energetica Molecolare

Description

The evaluation of gauge-invariant quantum transition probabilities for systems stimulated by external electromagnetic fields in general poses the problem of using a proper basis-defining hamiltonian operator, depending on the gauge chosen for introducing the effect of the external fields in the theoretical framework. A missed understanding of this point can lead to inconsistences, examples of which are presented and discussed for the case of a simple harmonic oscillator linearly driven by a time-dependent force. The behaviour of a quantum oscillator subjected (a) to a monochromatic field suddenly switched-on at a given time, (b) to a (short-duration) pulse is investigated exactly at high intensities and time-resolved gauge-invariant vs. ''conventional'' (i.e., generally false) transition probabilities are compared. In addition, approximation for these transition probabilities in terms of truncated bases of free-field harmonic oscillator eigenstates are derived and compared with the exact results

Additional details

Additional titles

Subtitle (English)
Harmonic oscillator

Publishing Information

Journal Title
Gazzetta Chimica Italiana
Journal Volume
118
Journal Issue
10
Series
Gazz. Chim. Ital.
Journal Page Range
703-713
ISSN
0016-5603
CODEN
GCITA

Optional Information

Notes
56 refs.