Conventional vs gauge invariant quantum transition probabilities in simple systems
Creators
- 1. Pisa Univ. (Italy). Dipt. di Chimica e Chimica Industriale
- 2. Consiglio Nazionale delle Ricerche, Pisa (Italy). Ist. di Chimica Quantistica ed Energetica Molecolare
Description
The evaluation of gauge-invariant quantum transition probabilities for systems stimulated by external electromagnetic fields in general poses the problem of using a proper basis-defining hamiltonian operator, depending on the gauge chosen for introducing the effect of the external fields in the theoretical framework. A missed understanding of this point can lead to inconsistences, examples of which are presented and discussed for the case of a simple harmonic oscillator linearly driven by a time-dependent force. The behaviour of a quantum oscillator subjected (a) to a monochromatic field suddenly switched-on at a given time, (b) to a (short-duration) pulse is investigated exactly at high intensities and time-resolved gauge-invariant vs. ''conventional'' (i.e., generally false) transition probabilities are compared. In addition, approximation for these transition probabilities in terms of truncated bases of free-field harmonic oscillator eigenstates are derived and compared with the exact results
Additional details
Additional titles
- Subtitle (English)
- Harmonic oscillator
Publishing Information
- Journal Title
- Gazzetta Chimica Italiana
- Journal Volume
- 118
- Journal Issue
- 10
- Series
- Gazz. Chim. Ital.
- Journal Page Range
- 703-713
- ISSN
- 0016-5603
- CODEN
- GCITA
INIS
- Country of Publication
- Italy
- Country of Input or Organization
- Italy
- INIS RN
- 20017022
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- ELECTRIC DIPOLE MOMENTS; ELECTROMAGNETIC FIELDS; ENERGY-LEVEL TRANSITIONS; GAUGE INVARIANCE; HAMILTONIANS; HARMONIC OSCILLATORS; LAMB SHIFT; MORSE POTENTIAL; QUANTUM MECHANICS
- Descriptors DEC
- DIPOLE MOMENTS; ELECTRIC MOMENTS; INVARIANCE PRINCIPLES; MATHEMATICAL OPERATORS; MECHANICS; POTENTIALS; QUANTUM OPERATORS; SPECTRAL SHIFT
Optional Information
- Notes
- 56 refs.