Published September 28, 1981 | Version v1
Journal article

Angular orientation of NH3 on Ni(111) by low-energy photoelectron scattering

  • 1. Department of Physics and Surface Studies Laboratory, University of Wisconsin, Milwaukee, Wisconsin 53201

Description

The azimuthal variations in the photoemission cross section for the le molecular orbital of NH3 adsorbed on Ni(111) are used to identify the angular orientation of the adsorbed molecules. From comparison of experiment and theory, it is possible to determine the NH-bond directions relative to the substrate. In addition, it is found that the observed strong azimuthal anisotropy comes mainly from direct interference of emissions from the le molecular orbital rather than from back-scattering off the substrate

Additional details

Publishing Information

Journal Title
Phys. Rev. Lett.
Journal Volume
47
Journal Issue
13
Series
Phys. Rev. Lett.
Journal Page Range
931-934
ISSN
0031-9007