Published August 1995
| Version v1
Journal article
New stoichiometric and structural data concerning the binary phases of the cesium-C60 fullerite system
Description
It has been shown that in thermodynamical equilibrium conditions only two binary intercalation cesium-C60 phases exist: a face centred cubic CsC60 and a body centred cubic Cs6C60 phases. They are adjacent in the phase diagram; from that point of view cesium differs clearly from rubidium and potassium, which both exhibit richer binary phase diagrams. For these alkali metals indeed there are, between MC60 and M6C60, two other phases with chemical formulas M3C60 and M4C60. While Cs4C60 seems never to have been mentioned before, the Cs3C60 appears as quite a controversial topic. (authors). 7 refs., 5 figs
Additional details
Additional titles
- Original title (French)
- Nouvelles donnees stoechiometriques et structurales concernant les phases binaires du systeme cesium-fullerite C
Publishing Information
- Journal Title
- Comptes Rendus de l'Academie des Sciences. Serie 2
- Journal Volume
- 321
- Journal Issue
- 3
- Journal Page Range
- p. 103-110.
- ISSN
- 0764-4450
- CODEN
- CRAMED
INIS
- Country of Publication
- France
- Country of Input or Organization
- France
- INIS RN
- 27018676
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALKALI METALS; BINARY MIXTURES; CESIUM; CLUSTER MODEL; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; CUBIC LATTICES; ELECTRICAL INSULATORS; FULLERENES; INTERMETALLIC COMPOUNDS; PHASE DIAGRAMS; POTASSIUM; RUBIDIUM; SOLID CLUSTERS; STOICHIOMETRY; STRUCTURAL CHEMICAL ANALYSIS; TEMPERATURE DEPENDENCE; THERMODYNAMICS; X-RAY DIFFRACTION
- Descriptors DEC
- ALLOYS; CARBON; COHERENT SCATTERING; DIAGRAMS; DIFFRACTION; DISPERSIONS; ELECTRICAL EQUIPMENT; ELEMENTS; EQUIPMENT; INFORMATION; MATHEMATICAL MODELS; METALS; MIXTURES; NONMETALS; NUCLEAR MODELS; SCATTERING