Published December 1986 | Version v1
Journal article Metadata-only

Reactivity toward alcohols of (RuIV = O2-) unit in trans-(RuCl(O)(py)4)+

Creators

  • 1. Jochi Univ., Tokyo (Japan). Faculty of Science and Technology

Description

The reactivity with alcohol of trans-[RuCl(O)(py)4]+ was investigated. In MeOH, trans-[RuCl(OH)(py)4]+ was confirmed to exist as a precursor in the formation of trans-[RuCl(OMe)(py)4]+. The reaction progress was traced by spectrometrical and 18O-labelling experiments. (author)

Additional details

Publishing Information

Journal Title
Chem. Lett. (Tokyo)
Journal Volume
1986
Journal Issue
12
Series
Chem. Lett. (Tokyo).
Journal Page Range
2135-2138
ISSN
0366-7022
CODEN
CMLTA

INIS

Country of Publication
Japan
Country of Input or Organization
Japan
INIS RN
18081894
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALCOHOLS; CATIONS; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; CHLORIDES; OXIDES; OXYGEN 18; PYRIDINES; RUTHENIUM COMPLEXES; SPECTROPHOTOMETRY; TRACER TECHNIQUES
Descriptors DEC
AZINES; CHALCOGENIDES; CHARGED PARTICLES; CHLORINE COMPOUNDS; COMPLEXES; EVEN-EVEN NUCLEI; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HYDROXY COMPOUNDS; IONS; ISOTOPE APPLICATIONS; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; OXYGEN ISOTOPES; REACTION KINETICS; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES