Published January 2005 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of KNa3[Fe2O(CH3COO)6(H2O2]3[α-P2W17Fe(H2O)O61]·32.5H2O

Creators

  • 1. SO RAN, Inst. Neorganicheskoj Khimii im. A.V. Nikolaeva, Novosibirsk (Russian Federation)
  • 2. Univ. La Laguna, Tenerife (Spain)

Description

The complex KNa3[Fe2O(CH3COO)6(H2O2]3[α-P2W17Fe(H2O)O61]·32.5H2O (1) was prepared in 52 % yield during interaction between iron(III) chloride and potassium tungstophosphate in acetate buffer, being characterized by data of IR spectroscopy and X-ray diffraction analysis. It was ascertained that complex 1 crystallizes in monoclinic crystal system, space group P2(1)/n, a=17.854(3), b=29.589(5), c=29.563(5) A, β=91.67(2) Deg, Z=4. In the crystal structure heteropolytungstate anions and iron trinuclear complex cations are bound by potassium and sodium cations into infinite zigzag-like chains

Abstract (Russian)

Комплекс KNa3[Fe2O(CH3COO)6(H2O2]3[α-P2W17Fe(H2O)O61]·32.5H2O (1) получен с выходом 52 % при взаимодействии хлорида железа(III) и фосфовольфрамата калия в ацетатном буфере и охарактеризован данными ИК спектроскопии и рентгеноструктурного анализа. Установлено, что комплекс 1 кристаллизуется в моноклинной сингонии, пр. гр. P2(1)/n, a=17.854(3), b=29.589(5), c=29.563(5) A, β=91.67(2) град, Z=4. В кристаллической структуре анионы гетерополивольфрамата и трехъядерные комплексные катионы железа связаны катионами калия и натрия в бесконечные зигзагообразные цепи

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллическая структура KNa

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
46
Journal Issue
1
Journal Page Range
p. 149-155
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36094753
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACETATES; BOND ANGLE; BOND LENGTHS; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; HYDRATES; INFRARED SPECTRA; IRON COMPLEXES; LATTICE PARAMETERS; MONOCLINIC LATTICES; POTASSIUM COMPOUNDS; SODIUM COMPOUNDS; TUNGSTOPHOSPHATES
Descriptors DEC
ALKALI METAL COMPOUNDS; CARBOXYLIC ACID SALTS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIMENSIONS; LENGTH; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; REFRACTORY METAL COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS; YIELDS

Optional Information

Notes
26 refs., 4 figs., 2 tabs.