Published March 1982 | Version v1
Journal article

Lead-containing stannatostibates of trivalent elements of PbA3SnSbO7 composition

  • 1. Kievskij Gosudarstvennyj Univ. (Ukrainian SSR)

Description

During heating of coprecipitated hydroxides in PbO atmosphere polycrystalline compounds of the composition PbA3 SnSbO7, where A3-Bi, rare earths (except Ce, Pm, Tm), In, Ga, Fe, Cr, Al, are prepared. For compositions with ion radii of A3 bigger than in indium pyrochlore structure is realized (sp. gr. Fd3m, a=10.60-10.41 A, Z=8). Compounds PbA3 SnSbO7, where A3-In, Sc, Ga, Fe, Cr, Al, are crystallized according to La3NbO7 type (sp. gr. Psub(nam), a=7.39-7.44 A, b=7.43-7.46 A, c=10.55-10.56 A, Z=4)

Additional details

Additional titles

Original title (Russian)
Свинецсодержащие станнатостибаты трехвалентных элементов состава PbA

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
27
Journal Issue
3
Series
Zh. Neorg. Khim.
Journal Page Range
661-664
ISSN
0044-457X

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).