Published April 10, 1986
| Version v1
Journal article
Fourier Transform infrared spectra of the 2nu2 and nu2 + nu4 bands of PH3
Description
The lowest-lying overtone (2nu2) and combination (nu2 + nu4) bands of phosphine have been investigated for the first time with a Fourier transform spectrometer with 0.01-cm-1 resolution. A least-squares fit which includes Coriolis coupling parameters has been performed on both bands simultaneously. The resulting constants fit 400 transitions with a standard deviation of 0.05 cm-1. Rotational parameters for the excited states and vibrational frequencies are obtained from the analysis. 17 references, 3 tables
Additional details
Publishing Information
- Journal Title
- J. Phys. Chem.
- Journal Volume
- 90
- Journal Issue
- 8
- Series
- J. Phys. Chem.
- Journal Page Range
- 1534-1537
- ISSN
- 0022-3654
- CODEN
- JPCHA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 17076422
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S79: ASTROPHYSICS, COSMOLOGY AND ASTRONOMY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; EXPERIMENTAL DATA; FOURIER TRANSFORMATION; HARMONICS; INFRARED SPECTRA; INFRARED SPECTROMETERS; PHOSPHINES; ROTATIONAL STATES; VIBRATIONAL STATES
- Descriptors DEC
- DATA; ENERGY LEVELS; EXCITED STATES; INFORMATION; INTEGRAL TRANSFORMATIONS; MEASURING INSTRUMENTS; NUMERICAL DATA; OSCILLATIONS; PHOSPHORUS COMPOUNDS; SPECTRA; SPECTROMETERS; SPECTROSCOPY; TRANSFORMATIONS