Published October 2023 | Version v1
Journal article

Green biochar-based adsorbent for radiocesium and Cu, Ni, and Pb removal

  • 1. Trnava University in Trnava, Trnava (Slovakia). Department of Chemistry, Faculty of Education
  • 2. Slovak University of Technology in Bratislava, Trnava (Slovakia). Institute of Materials Science, Faculty of Materials Science and Technology in Trnava
  • 3. Technical University of Kosice, Kosice (Slovakia). Institute of Earth Resources, Faculty of Mining, Ecology, Process Control and Geotechnologies
  • 4. University of Natural Resources and Life Sciences, Vienna (Austria). Institute for Chemical and Energy Engineering
  • 5. AIT Austrian Institute of Technology GmbH, Tulln an Der Donau (Austria). Energy Department

Description

Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was characterized by XPS, SEM-EDX, and FT-IR analyses. The biochar's adsorption capacity was 20.5(Cs), 25.2(Cu), 12.4(Ni), and 45.9(Pb) mg g-1 and demonstrated satisfactory performance for different pH values. The kinetics data evaluation revealed that besides chemisorption, intraparticle diffusion contributes to metal removal. Moreover, the physical and structural properties of biochar play an important role in adsorption. Results indicate the suitability of using GW biochar as an alternative sorbent for both radionuclides and metal extraction. (author)

Additional details

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
332
Journal Issue
10
Journal Page Range
p. 4141-4155
ISSN
0236-5731
CODEN
JRNCDM

INIS

Country of Publication
Hungary
Country of Input or Organization
Hungary
INIS RN
54108041
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ADSORPTION; CESIUM; CHARCOAL; HEAVY METALS; ORGANIC WASTES; RADIOISOTOPES; THERMOCHEMICAL PROCESSES
Descriptors DEC
ADSORBENTS; ALKALI METALS; ELEMENTS; ISOTOPES; METALS; SORPTION; WASTES

Optional Information

Notes
63 refs.