Published November 28, 2014
| Version v1
Journal article
Rotational averaging of multiphoton absorption cross sections
- 1. Centre for Theoretical and Computational Chemistry, University of Tromsø — The Arctic University of Norway, N-9037 Tromsø (Norway)
Description
Rotational averaging of tensors is a crucial step in the calculation of molecular properties in isotropic media. We present a scheme for the rotational averaging of multiphoton absorption cross sections. We extend existing literature on rotational averaging to even-rank tensors of arbitrary order and derive equations that require only the number of photons as input. In particular, we derive the first explicit expressions for the rotational average of five-, six-, and seven-photon absorption cross sections. This work is one of the required steps in making the calculation of these higher-order absorption properties possible. The results can be applied to any even-rank tensor provided linearly polarized light is used
Additional details
Identifiers
- DOI
- 10.1063/1.4901563;
Publishing Information
- Journal Title
- Journal of Chemical Physics
- Journal Volume
- 141
- Journal Issue
- 20
- Journal Page Range
- p. 204103-204103.8
- ISSN
- 0021-9606
- CODEN
- JCPSA6
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 46119099
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION; CROSS SECTIONS; MULTI-PHOTON PROCESSES; PHOTONS
- Descriptors DEC
- BOSONS; ELEMENTARY PARTICLES; MASSLESS PARTICLES; SORPTION
Optional Information
- Notes
- (c) 2014 AIP Publishing LLC