Published November 28, 2014 | Version v1
Journal article

Rotational averaging of multiphoton absorption cross sections

  • 1. Centre for Theoretical and Computational Chemistry, University of Tromsø — The Arctic University of Norway, N-9037 Tromsø (Norway)

Description

Rotational averaging of tensors is a crucial step in the calculation of molecular properties in isotropic media. We present a scheme for the rotational averaging of multiphoton absorption cross sections. We extend existing literature on rotational averaging to even-rank tensors of arbitrary order and derive equations that require only the number of photons as input. In particular, we derive the first explicit expressions for the rotational average of five-, six-, and seven-photon absorption cross sections. This work is one of the required steps in making the calculation of these higher-order absorption properties possible. The results can be applied to any even-rank tensor provided linearly polarized light is used

Additional details

Identifiers

Publishing Information

Journal Title
Journal of Chemical Physics
Journal Volume
141
Journal Issue
20
Journal Page Range
p. 204103-204103.8
ISSN
0021-9606
CODEN
JCPSA6

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
46119099
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION; CROSS SECTIONS; MULTI-PHOTON PROCESSES; PHOTONS
Descriptors DEC
BOSONS; ELEMENTARY PARTICLES; MASSLESS PARTICLES; SORPTION

Optional Information

Notes
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