Published August 1986
| Version v1
Journal article
Mononuclear oxo- and hydroxo complexes of molybdenum (5)
- 1. Kievskij Politekhnicheskij Inst. (Ukrainian SSR)
Description
Constants of molybdenum (5) ion hydrolysis in perchlorate solutions are determined and phase diagram of its oxo- and hydroxo complexes is plotted. It follows from the diagram that MoO2+ cations dominate in a wide range of pH value from pH3 to 2-3 mol/l HClO4. In less acid solutions MoO2OH hydroxo complexes are formed, in more acid solutions - unstable MoO3+ cations frequenty oxidized to molybdenum blue
Additional details
Additional titles
- Original title (Russian)
- Моноядерные оксо- и гидроксокомплексы молибдена (5)
Publishing Information
- Journal Title
- Zh. Neorg. Khim.
- Journal Volume
- 31
- Journal Issue
- 8
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 1989-1991
- ISSN
- 0044-457X
- CODEN
- ZNOKA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 18035064
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CHEMICAL STATE; HYDROLYSIS; MOLYBDENUM COMPLEXES; MOLYBDENUM COMPOUNDS; PERCHLORIC ACID; PH VALUE; QUANTITY RATIO; STABILITY; THIOCYANATES
- Descriptors DEC
- ANTITHYROID DRUGS; CARBONIC ACID DERIVATIVES; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; DECOMPOSITION; DISPERSIONS; DRUGS; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; MIXTURES; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; SOLUTIONS; SOLVOLYSIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Russian Journal of Inorganic Chemistry (UK).