Radiative transition probabilities for the A 1Σ--X 1Σ+ bands of 7LiH
Description
The recently reported (J. Chem. Phys. 66, 5412 (1977)) hybrid potential curves for the X 1Σ+ and A 1Σ+ states of LiH are combined with the ab initio transition moments of Docken and Hinze (J. Chem. Phys. 57, 4936 (1972)) to calculate radiative transition probabilities between all upper (v' < or = 26) and all lower (v'' < or = 23) vibrational levels of 7LiH. By far the strongest single band found is the 23 to 26 band between the highest ''long-range'' levels in each potential. A comparison with experimental intensity observations is made; it appears that the experiments are globally in accord with calculations, but with some detailed differneces discussed herein
Availability note (English)
MF available from INIS under the Report Number; Available from NTIS., PC A03/MF A01.
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Additional details
Additional titles
- Augmented title (English)
- Tables
Publishing Information
- Imprint Pagination
- 40 p.
- Report number
- COO--2326-22
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 9387422
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- BAND THEORY; ENERGY-LEVEL TRANSITIONS; LITHIUM HYDRIDES; LITHIUM 7; POTENTIAL ENERGY; TABLES; VIBRATIONAL STATES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ENERGY; ENERGY LEVELS; EXCITED STATES; HYDRIDES; HYDROGEN COMPOUNDS; INFORMATION; ISOTOPES; LIGHT NUCLEI; LITHIUM COMPOUNDS; LITHIUM ISOTOPES; NUCLEI; ODD-EVEN NUCLEI; STABLE ISOTOPES