There is a newer version of the record available.

Published December 7, 1998 | Version v1
Report

Electrochemical Studies of Nitrate-Induced Pitting in Carbon Steel

Description

The phenomenon of pitting in carbon steel exposed to alkaline solutions of nitrate and chloride was studied with the cyclic potentiodynamic polarization technique. Open-circuit and pitting potentials were measured on specimens of ASTM A537 carbon steel in pH 9.73 salt solutions at 40 degrees Celsius, with and without the inhibiting nitrite ion present. Nitrate is not so aggressive a pitting agent as is chloride. Both nitrate and chloride did induce passive breakdown and pitting in nitrite-free solutions, but the carbon steel retained passivity in solutions with 0.11-M nitrite even at a nitrate concentration of 2.2 M

Availability note (English)

Available from OSTI; NTIS; URL:http://www.srs.gov/general/sci-tech/fulltext/ms9800865/ms9800865.html; US Govt. Printing Office Dep.

Additional details

Publishing Information

Imprint Pagination
[vp]
Report number
WSRC-MS--98-00865

Conference

Title
NACE International Corrosion '99
Dates
25-30 Apr 1999
Place
San Antonio, TX (United States)

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
30061394
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference, Non-conventional Literature
Descriptors DEI
AQUEOUS SOLUTIONS; CARBON STEELS; CHLORIDES; MEETINGS; NITRATES; PASSIVITY; PITTING CORROSION; TEMPERATURE RANGE 0273-0400 K
Descriptors DEC
ALLOYS; CARBON ADDITIONS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; CORROSION; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; IRON ALLOYS; IRON BASE ALLOYS; MIXTURES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; SOLUTIONS; STEELS; TEMPERATURE RANGE; TRANSITION ELEMENT ALLOYS

Optional Information

Contract/Grant/Project number
Contract AC09-96SR18500
Funding organization
DOE (United States)