Electrochemical Studies of Nitrate-Induced Pitting in Carbon Steel
Description
The phenomenon of pitting in carbon steel exposed to alkaline solutions of nitrate and chloride was studied with the cyclic potentiodynamic polarization technique. Open-circuit and pitting potentials were measured on specimens of ASTM A537 carbon steel in pH 9.73 salt solutions at 40 degrees Celsius, with and without the inhibiting nitrite ion present. Nitrate is not so aggressive a pitting agent as is chloride. Both nitrate and chloride did induce passive breakdown and pitting in nitrite-free solutions, but the carbon steel retained passivity in solutions with 0.11-M nitrite even at a nitrate concentration of 2.2 M
Availability note (English)
Available from OSTI; NTIS; URL:http://www.srs.gov/general/sci-tech/fulltext/ms9800865/ms9800865.html; US Govt. Printing Office Dep.Additional details
Publishing Information
- Imprint Pagination
- [vp]
- Report number
- WSRC-MS--98-00865
Conference
- Title
- NACE International Corrosion '99
- Dates
- 25-30 Apr 1999
- Place
- San Antonio, TX (United States)
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 30061394
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Conference, Non-conventional Literature
- Descriptors DEI
- AQUEOUS SOLUTIONS; CARBON STEELS; CHLORIDES; MEETINGS; NITRATES; PASSIVITY; PITTING CORROSION; TEMPERATURE RANGE 0273-0400 K
- Descriptors DEC
- ALLOYS; CARBON ADDITIONS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; CORROSION; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; IRON ALLOYS; IRON BASE ALLOYS; MIXTURES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; SOLUTIONS; STEELS; TEMPERATURE RANGE; TRANSITION ELEMENT ALLOYS
Optional Information
- Contract/Grant/Project number
- Contract AC09-96SR18500
- Funding organization
- DOE (United States)