Published September 2008 | Version v1
Journal article Metadata-only

Photophysical properties of the d 0 π-complex in binary media

Creators

  • 1. RAN, Inst. Problem Khimicheskoj Fiziki, Chernogolovka, Moskovskaya Obl. (Russian Federation)

Description

The luminescent properties of a d0 metal complex rac-C6H10(IndH4)2ZrCl2 (IndH4 = tetrahydroindenyl) in binary aprotic media in which preferential solvation can occur were studied at room temperature. It was shown that the luminescence quantum yield for the complex in liquid solutions is sensitive to changes in the multilayer solvation shell

Abstract (Russian)

Исследованы люминесцентные свойства d0 металлокомплекса рац-C6H10(IndH4)2ZrCl2 (IndH4 - тетрагидроинденил) в бинарных апротонных средах, в которых может происходить выборочная сольватация, при комнатной температуре. Показано, что квантовый выход люминесценции целевого комплекса чувствителен к изменениям в многослойной сольватной оболочке в жидких растворах

Additional details

Additional titles

Original title (Russian)
Фотофизические свойства д

Publishing Information

Journal Title
Khimiya Vysokikh Ehnergij
Journal Volume
42
Journal Issue
5
Journal Page Range
p. 413-419
ISSN
0023-1193
CODEN
KHVKAO

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
40088780
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; CHLORIDES; CONCENTRATION RATIO; CONDENSED AROMATICS; CYCLOALKANES; LUMINESCENCE; METHYLENE CHLORIDE; MIXED SOLVENTS; SOLUTIONS; SOLVATION; TEMPERATURE RANGE 0273-0400 K; TOLUENE; ZIRCONIUM COMPLEXES
Descriptors DEC
ALKANES; ALKYLATED AROMATICS; AROMATICS; CHLORINE COMPOUNDS; COMPLEXES; DIMENSIONLESS NUMBERS; DISPERSIONS; EMISSION; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROCARBONS; MIXTURES; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PHOTON EMISSION; SOLVENTS; SPECTRA; TEMPERATURE RANGE; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
17 refs., 5 figs.