Published 2010 | Version v1
Miscellaneous

Development of reference electrode using zirconium as electrode pole to measure electrochemical corrosion potential in high temperature pure water

  • 1. Hitachi Ltd., Energy and Environmental Systems Lab., Hitachi-shi, Ibaraki-ken (Japan)
  • 2. Hitachi-GE Nuclear Energy, Ltd., Hitachi-shi, Ibaraki-ken (Japan)

Description

A new reference electrode using zirconium (Zr electrode) was developed for long term monitoring of electrochemical corrosion potential (ECP) of reactor structural materials in boiling water reactors (BWRs). ECPs of the Zr electrode were constant for 280-285 oC water containing dissolved hydrogen of 40 ppb and hydrogen peroxide 0 - 900ppb or dissolved oxygen 0 - 7000 ppb. ECPs of 316L stainless steel measured by using the Zr electrode were in good agreement with those measured by using a silver-silver chloride external reference electrode within ±0.03V. (author)

Availability note (English)

Available as a slide presentation also.
Part of:
Nuclear power plant conference 2010 (NPC 2010): International conference on water chemistry of nuclear reactor systems and 8th International radiolysis, electrochemistry and materials performance workshop

Additional details

Publishing Information

Publisher
Canadian Nuclear Society
Imprint Place
Toronto, Ontario (Canada)
ISBN
978-1-926773-00-1
Imprint Title
Nuclear power plant conference 2010 (NPC 2010): International conference on water chemistry of nuclear reactor systems and 8th International radiolysis, electrochemistry and materials performance workshop
Imprint Pagination
278 Megabytes
Journal Page Range
[8 p.]

Conference

Title
8. International radiolysis workshop proceedings
Dates
3-8 Oct 2010
Place
Quebec City, Quebec (Canada)

Optional Information

Notes
Paper 5.01, 8 refs., 2 tabs., 8 figs.