Magneto-caloric effect in the pseudo-binary intermetallic YPrFe17 compound
Creators
- 1. Departamento de Física, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain)
- 2. División de Materiales Avanzados, Instituto Potosino de Investigación Científica y Tecnológica, Camino a la presa San José 2055, CP 78216, San Luis Potosí (Mexico)
- 3. Departamento de Física de la Materia Condensada, ICMSE-CSIC, Universidad de Sevilla, P.O. Box 1065, 41080 Sevilla (Spain)
- 4. Institute of Experimental Physics, Watsonova 47, SK-04001 Košice (Slovakia)
- 5. Institute Laue Langevin, 6 rue Jules Horowitz, 38042 Grenoble (France)
Description
Highlights: ► YPrFe17 exhibits a broad ΔSM(T) associated with the ferro-to-paramagnetic phase transition (TC ≈ 290 K). ► We obtain |ΔSM| ≈2.3 J kg−1 K−1 and RCP≈100 J kg−1for a magnetic field change of 1.5 T. ► A single master curve for ΔSM is found when compared with other isostructural R2Fe17 binary alloys. - Abstract: We have synthesized the intermetallic YPrFe17 compound by arc-melting. X-ray and neutron powder diffraction show that the crystal structure is rhombohedral with R3¯m space group (Th2Zn17-type). The investigated compound exhibits a broad isothermal magnetic entropy change ΔSM(T) associated with the ferro-to-paramagnetic phase transition (TC ≈ 290 K). The |ΔSM| (≈2.3 J kg−1 K−1) and the relative cooling power (≈100 J kg−1) have been calculated for applied magnetic field changes up to 1.5 T. A single master curve for ΔSM under different values of the magnetic field change can be obtained by a rescaling of the temperature axis. The results are compared and discussed in terms of the magneto-caloric effect in the isostructural R2Fe17 (R = Y, Pr and Nd) binary intermetallic alloys.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.matchemphys.2011.09.062Additional details
Identifiers
- DOI
- 10.1016/j.matchemphys.2011.09.062;
- arXiv
- arXiv:1201.4411v1;
- PII
- S0254-0584(11)00822-4;
Publishing Information
- Journal Title
- Materials Chemistry and Physics
- Journal Volume
- 131
- Journal Issue
- 1-2
- Journal Page Range
- p. 18-22
- ISSN
- 0254-0584
- CODEN
- MCHPDR
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 44025201
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- BINARY ALLOY SYSTEMS; COOLING; ENTROPY; INTERMETALLIC COMPOUNDS; IRON ALLOYS; MAGNETIC FIELDS; MAGNETIC MATERIALS; MELTING; NEUTRON DIFFRACTION; PARAMAGNETISM; PRASEODYMIUM ALLOYS; TRIGONAL LATTICES; X-RAY DIFFRACTION; YTTRIUM ALLOYS
- Descriptors DEC
- ALLOY SYSTEMS; ALLOYS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; MAGNETISM; MATERIALS; PHASE TRANSFORMATIONS; PHYSICAL PROPERTIES; RARE EARTH ALLOYS; SCATTERING; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT ALLOYS
Optional Information
- Copyright
- Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.