Development of a viable route for lithium-6 supply of DEMO and future fusion power plants

In the European DEMO program, the design development of a demonstration power plant (DEMO) is currently in its pre-conceptual phase. In DEMO, breeding blankets will use large quantities of lithium, enriched in the isotope lithium-6 (⁶Li), for breeding the tritium needed to feed the DT fusion reaction. Unfortunately, enriched lithium is commercially not available in the required quantities, which is threatening the success of future power plant applications of nuclear fusion. Even if the manufacturing of the breeding blankets is still two decades ahead of us, it is now mandatory to address the topic of lithium-6 supply and to make sure that a viable supply (and reprocessing) route is available when needed. This paper presents an unbiased systems engineering approach assessing a number of available lithium isotope separation methods by defining requirements, rating them systematically and finally calculating a ranking number expressing the value of different methods. As a result, we suggest using a chemical exchange method based on a lithium amalgam system, but including some important improvements leading to a more efficient and 'clean' process (the ICOMAX process) in comparison with the formerly used COLEX process. Furthermore, by modelling activities and experiments in the KIT mercury laboratory (HgLab Karlsruhe), it is shown which work has to be done in the next years to make sure that the technical-scale process is available in time to supply DEMO and future fusion power plants by middle of the 21^st century.