Published 1996
| Version v1
Journal article
Reaction of carbon dioxide with zirconocene and hafnocene dihydrides
- 1. AN SSSR, Moscow (Russian Federation). Inst. Ehlementoorganicheskikh Soedinenij
- 2. AN SSSR, Moscow (Russian Federation). Otdelenie Obshchej i Tekhnicheskoj Khimii
Description
Zirconocene and hafnocene dihydrides Cp2MH2 (M = Zr, Hf) rapidly absorb carbon dioxide at room temperature and atmospheric pressure in a THF medium. In the case of Cp2ZrH2, reaction results in the splitting of C = O bond of the CO2 molecule to from cyclic trimeric zirconocene oxide [Cp2ZrO]3 whose structure was proved by analytical and spectral methods as well as X-ray diffraction study. 13 refs
Additional details
Additional titles
- Original title (Russian)
- Взаимодействие углекислого газа с дигидридами цирконоцена и гафноцена
Publishing Information
- Journal Title
- Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
- Journal Issue
- no.9
- Journal Page Range
- p. 2366-2368.
- ISSN
- 1026-3500
- CODEN
- IASKEA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 28033065
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CARBON DIOXIDE; CHEMICAL REACTION YIELD; CHEMICAL REACTIONS; CYCLOPENTADIENE; HAFNIUM COMPLEXES; HYDRIDES; INFRARED SPECTRA; MOLECULAR STRUCTURE; NMR SPECTRA; OXIDES; PROTONS; SOLUTIONS; TETRAHYDROFURAN; ZIRCONIUM COMPLEXES
- Descriptors DEC
- ALKENES; BARYONS; CARBON COMPOUNDS; CARBON OXIDES; CATIONS; CHALCOGENIDES; CHARGED PARTICLES; COMPLEXES; CYCLOALKENES; DIENES; DISPERSIONS; ELEMENTARY PARTICLES; FERMIONS; FURANS; HADRONS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; IONS; MIXTURES; NUCLEONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; POLYENES; SPECTRA; TRANSITION ELEMENT COMPLEXES; YIELDS