Published March 1993 | Version v1
Journal article Metadata-only

Hydroxylamines - new decarbonylation reagents in the synthesis of carbonyl complex derivatives. Crystal structure of (μ-H)Os3(μ-OCNHCH2COOEt)(CO)9(NH2CH3)

Creators

  • 1. AN SSSR, Novosibirsk (Russian Federation). Inst. Neorganicheskoj Khimii

Description

Reaction of a series of mononuclear and cluster carbonyl complexes of transition metals (including Mo, W) with aminocompounds in the presence of H2O2 has been investigated. Synthesis of Mo(CO)5NH3 and W(CO)5NH3 has been described. The complexes are characterized by chemical analysis and IR-spectroscopy data

Additional details

Additional titles

Original title (Russian)
Гидроксиламины - новые декарбонилирующие реагенты в синтезе производных карбонильных комплексов. Кристаллическая структура (μ-Х)Ос

Publishing Information

Journal Title
Metalloorganicheskaya Khimiya
Journal Volume
6
Journal Issue
2
Journal Page Range
p. 231-242.
ISSN
0235-0114
CODEN
MEKHEX

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
24074130
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIA; CARBONYLS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; MELTING POINTS; MOLYBDENUM; TUNGSTEN COMPLEXES
Descriptors DEC
COMPLEXES; ELEMENTS; HYDRIDES; HYDROGEN COMPOUNDS; METALS; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; PHYSICAL PROPERTIES; SYNTHESIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS; TRANSITION TEMPERATURE; YIELDS