Published November 4, 2011 | Version v1
Journal article Metadata-only

Carbon dioxide insertion into uranium-activated dicarbonyl complexes

Creators

  • 1. Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Inorganic Chemistry, Erlangen (Germany)

Description

Uranium(III) complexes bearing hexadentate triazacyclononane macrocyclic ligands L1 engage di- and triketones in both one- and two-electron reduction pathways. The dinuclear enolate generated through one of these pathways reacts with carbon dioxide to generate a new C-C bond. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/anie.201104189

Additional details

Identifiers

DOI
10.1002/anie.201104189;

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
50
Journal Issue
45
Journal Page Range
p. 10626-10630
ISSN
1433-7851
CODEN
ACIEF5

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48046083
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBON DIOXIDE; CHEMICAL BONDS; CRYSTALLOGRAPHY; LIGANDS; ORGANOMETALLIC COMPOUNDS; URANIUM COMPLEXES; X-RAY DIFFRACTION
Descriptors DEC
ACTINIDE COMPLEXES; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; COHERENT SCATTERING; COMPLEXES; DIFFRACTION; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SCATTERING

Optional Information

Notes
With 7 figs., 1 tab., 53 refs.