Published 1978
| Version v1
Journal article
Vibrational spectra of transition metal coordination compounds with thio- and seleno-ligands. Part 10. Pd(2), Pt(2), Zn(2), Cd(2), Hg(2), Mn(2) complexes of dithiocarbazic acid
Creators
- 1. Politechnika Wroclawska (Poland). Inst. Chemii Nieorganicznej i Metalurgii Pierwiastkow Rzadkich
Description
The IR and Raman spectra of the Pd(2), Pt(2), Zn(2), Cd(2), Hg(2), Mn(2) complexes with dithiocarbazic acid have been discussed. Band assignments have been made on the basis of the metal-isotope substitution (64Zn-68Zn) and N-deuteration data. It was concluded that all complexes are N,S-coordinated; Pd(2) and Pt(2) compounds are of trans squareplanar structure, while Zn(2), Cd(2), Hg(2) and Mn(2) complexes are of a pseudotetrahedral structure. (author)
Additional details
Publishing Information
- Journal Title
- Bull. Acad. Pol. Sci., Ser. Sci. Chim.
- Journal Volume
- 26
- Journal Issue
- 1
- Series
- Bull. Acad. Pol. Sci., Ser. Sci. Chim.
- Journal Page Range
- 63-71
- ISSN
- 0001-4095
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 12604141
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CADMIUM COMPLEXES; CARBAZIDES; DEUTERATION; DEUTERIUM COMPOUNDS; EXPERIMENTAL DATA; INFRARED SPECTRA; ORGANIC SULFUR COMPOUNDS; RAMAN SPECTRA; SPECTRAL SHIFT; VIBRATIONAL STATES; ZINC COMPLEXES; ZINC 64; ZINC 68
- Descriptors DEC
- CARBONIC ACID DERIVATIVES; CHEMICAL REACTIONS; COMPLEXES; DATA; ENERGY LEVELS; EVEN-EVEN NUCLEI; EXCITED STATES; HYDROGEN COMPOUNDS; INFORMATION; INTERMEDIATE MASS NUCLEI; ISOTOPES; NUCLEI; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SPECTRA; STABLE ISOTOPES; ZINC ISOTOPES