Published March 2005
| Version v1
Journal article
Generation of the first representatives of the Schrock complexes of heavy carbene analogs
- 1. RAN, Inst. Organicheskoj Khimii im. N. D. Zelinskogo, Moscow (Russian Federation)
- 2. RAN, Inst. Metalloorganicheskoj Khimii im. G. A. Razuvaeva, Nizhnij Novgorod (Russian Federation)
Description
The reactions of vanadocene, Cp2V, or decamethylvanadocene, Cp*2V, with 7,7-dimethyl-7-silanorbornadiene or 7,7-dimethyl-7-germanorbornadiene derivatives were studied by ESR in organic solvents. The reactions afforded the first representatives of Schrock complexes of heavy carbene analogs with transition metals. It is shown that decamethylvanadocene can be used as a paramagnetic trap for short-lived dimethylgermylene
Abstract (Russian)
Методом ЭПР в растворе органических растворителей изучены реакции ванадоцена (Cp2V) и декаметилванадоцена (Cp*2V) с производными 7,7-диметил-7-силанорборнадиена и 7,7-диметил-7-германорборнадиена. В результате этих реакций первые получены представители комплексов тяжелых аналогов карбенов с переходными металлами шроковского типа. Показано, что декаметилванадоцен может быть использован в качестве парамагнитной ловушки для короткоживущего диметилгермиленаAdditional details
Additional titles
- Original title (Russian)
- Генерирование первых представителей комплексов Шрока тяжелых аналогов карбенов
Publishing Information
- Journal Title
- Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
- Journal Issue
- no.3
- Journal Page Range
- p. 792-795
- ISSN
- 1026-3500
- CODEN
- IASKEA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 36100265
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AROMATICS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CYCLOALKENES; ELECTRON SPIN RESONANCE; GERMANIUM COMPOUNDS; HETEROCYCLIC COMPOUNDS; MOLECULAR STRUCTURE; ORGANIC SILICON COMPOUNDS; ORGANOMETALLIC COMPOUNDS; SPECTRA; VANADIUM COMPLEXES
- Descriptors DEC
- ALKENES; COMPLEXES; HYDROCARBONS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; RESONANCE; SYNTHESIS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- 17 refs., 1 fig.