Source signatures from combined isotopic analyses of PM2.5 carbonaceous and nitrogen aerosols at the peri-urban Taehwa Research Forest, South Korea in summer and fall

Highlights: • For PM_2.5, the average δ¹³C of TC and δ¹⁵N of TN were −25.4 ± 0.7‰ and 14.6 ± 3.8‰respectively. • EC and TC were dominated by fossil-fuel (78 ± 7%) and contemporary (76 ± 7%) sources, respectively. • Low δ¹⁵N (7.0 ± 0.2‰) with high TN concentration was evident in air masses from Shandong province. • Multi-isotopic composition is useful to trace regional sources of PM_2.5 aerosol. -- Abstract: Isotopes are essential tools to apportion major sources of aerosols. We measured the radiocarbon, stable carbon, and stable nitrogen isotopic composition of PM_2.5 at Taehwa Research Forest (TRF) near Seoul Metropolitan Area (SMA) during August–October 2014. PM_2.5, TC, and TN concentrations were 19.4 ± 10.1 μg m⁻³, 2.6 ± 0.8 μg C m⁻³, and 1.4 ± 1.4 μg N m⁻³, respectively. The δ¹³C of TC and the δ¹⁵N of TN were − 25.4 ± 0.7‰ and 14.6 ± 3.8‰, respectively. EC was dominated by fossil-fuel sources with F_ff (EC) of 78 ± 7%. In contrast, contemporary sources were dominant for TC with F_c (TC) of 76 ± 7%, revealing the significant contribution of contemporary sources to OC during the growing season. The isotopic signature carries more detailed information on sources depending on air mass trajectories. The urban influence was dominant under stagnant condition, which was in reasonable agreement with the estimated δ¹⁵N of NH₄⁺. The low δ¹⁵N (7.0 ± 0.2‰) with high TN concentration was apparent in air masses from Shandong province, indicating fossil fuel combustion as major emission source. In contrast, the high δ¹⁵N (16.1 ± 3.2‰) with enhanced TC/TN ratio reveals the impact of biomass burning in the air transported from the far eastern border region of China and Russia. Our findings highlight that the multi-isotopic composition is a useful tool to identify emission sources and to trace regional sources of carbonaceous and nitrogen aerosols.