Published August 31, 2008 | Version v1
Journal article

Photodissociation of aromatic azides

Creators

  • 1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region (Russian Federation)

Description

Quantitative data on the photochemical activity of aromatic azides and on the mechanism and kinetics of azido group photodissociation are analysed and described systematically for the first time. The results of quantum chemical calculations of the azide structure in the ground and lower electronically excited states and the potential energy surfaces along the reaction coordinate of the N-N2 bond dissociation are considered.

Availability note (English)

Available from http://dx.doi.org/10.1070/RC2008v077n08ABEH003793

Additional details

Publishing Information

Journal Title
Russian Chemical Reviews (Print)
Journal Volume
77
Journal Issue
8
Journal Page Range
p. 709-723
ISSN
0036-021X

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
41014010
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AZIDES; COORDINATES; DISSOCIATION; EXCITED STATES; KINETICS; PHOTOCHEMISTRY; PHOTOLYSIS; POTENTIAL ENERGY; SURFACES
Descriptors DEC
CHEMICAL REACTIONS; CHEMISTRY; DECOMPOSITION; ENERGY; ENERGY LEVELS; NITROGEN COMPOUNDS; PHOTOCHEMICAL REACTIONS