Crystal structure of the Ag2SiS3 compound
- 1. Department of Inorganic and Physical Chemistry, Volyn National University, Voli Ave 13, Lutsk 43025 (Ukraine)
- 2. Department of Inorganic and Organic Chemistry, Lviv National University of Veterinary Medicine and Biotechnologies, Pekarska St., 50, Lviv 79010 (Ukraine)
- 3. Electrical Engineering Department, Czestochowa Technological University, Al. Armii Krajowej 17, Czestochowa (Poland)
Description
Research highlights: → The crystal structure of the ternary compound Ag2SiS3 was determined on the basis of X-ray powder diffraction pattern. → The title compound crystallizes in a new structure type: space group P21/c, a = 0.66709(1), b = 0.66567(2), c = 1.31748(3) nm, and β = 118.658(1)o. → The crystal structure of Ag2SiS3 consists of isolated [Si2S6]4- anionic units of pairs of edge-shared tetrahedra. The Ag atoms are situated in the interstices formed by these fragments. - Abstract: The crystal structure of the ternary compound Ag2SiS3 was determined on the basis of X-ray powder diffraction. The compound belongs to a new structure type, space group P21/c, a = 0.66709(1), b = 0.66567(2), c = 1.31748(3) nm, and β = 118.658(1)o. Ag2SiS3 contains isolated [Si2S6] anionic units consisting of pairs of edge-shared tetrahedra. The Ag atoms are situated in the interstices formed by these fragments.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jallcom.2010.11.100Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2010.11.100;
- PII
- S0925-8388(10)02863-X;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 509
- Journal Issue
- 12
- Journal Page Range
- p. 4372-4374
- ISSN
- 0925-8388
- CODEN
- JALCEU
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 43008299
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- MONOCLINIC LATTICES; SILICON; SILVER; SOLIDS; SPACE GROUPS; SULFUR; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; ELEMENTS; METALS; NONMETALS; SCATTERING; SEMIMETALS; SYMMETRY GROUPS; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.