Published 2012 | Version v1
Miscellaneous

Effects of grain size and CeO2 addition on the corrosion behaviour of Cr2O3 based ceramics in high temperature supercritical water environment

  • 1. Univ. of Alberta, Dept. of Chemical and Materials Engineering, Edmonton, Alberta (Canada)
  • 2. MTL-NRCan, Ottawa, Ontario (Canada)
  • 3. Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

Description

In this investigation, Cr2O3 ceramics with different grain sizes were prepared and tested in supercritical water (SCW) environment at 650°C /25 MPa for 200 hours. The results show that the stability of Cr2O3 in SCW was affected by its grain size. In addition, various amounts of CeO2 were added to Cr2O3 to examine the effect of CeO2 on the corrosion behaviour of the Cr2O3 based ceramic under SCW condition. These Cr2O3-based ceramics were exposed to an SCW environment at 650°C/ 25 MPa for up to 600 hours. The results showed that adding a proper amount (≤ 5 wt. %) of CeO2 increased the corrosion resistance of Cr2O3-based ceramics in SCW. (author)

Part of:
Building on our past... building for the future. 33rd Annual Canadian Nuclear Society conference and 36th CNS/CNA student conference

Additional details

Publishing Information

Publisher
Canadian Nuclear Society
Imprint Place
Toronto, Ontario (Canada)
ISBN
978-1-926773-094
Imprint Title
Building on our past... building for the future. 33rd Annual Canadian Nuclear Society conference and 36th CNS/CNA student conference
Imprint Pagination
189 Megabytes
Journal Page Range
[5 p.]

Conference

Title
33. Annual Canadian Nuclear Society conference; 36. CNS/CNA student conference
Dates
10-13 Jun 2012
Place
Saskatoon, Saskatchewan (Canada)

INIS

Country of Publication
Canada
Country of Input or Organization
Canada
INIS RN
47018176
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference, Non-conventional Literature
Descriptors DEI
CERAMICS; CERIUM OXIDES; CHROMIUM OXIDES; CORROSION; CORROSION RESISTANCE; GRAIN SIZE; TURBULENT FLOW
Descriptors DEC
CERIUM COMPOUNDS; CHALCOGENIDES; CHEMICAL REACTIONS; CHROMIUM COMPOUNDS; FLUID FLOW; MICROSTRUCTURE; OXIDES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; SIZE; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
7 refs., 2 tabs., 5 figs.