Published February 2008 | Version v1
Journal article Metadata-only

Anionic complexes of Cu(I) with the closo-decaborate anion

Creators

  • 1. Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova RAN, Moscow (Russian Federation)

Description

General procedures for synthesis of anionic Cu(I) complexes with the closo-decaborate anion were worked out; they make it possible to prepare coordination compounds with a wide set of organic cations. The interaction of onium closo-decaborates with [Cu2B10H10] in acetonitrile acidified with anhydrous trifluoroacetic acid was found to be the most effective synthetic method that secures high yield and quality of the obtained products. The structure of {(C2H5)3NH[CuB10H10]} was determined by X-ray diffraction analysis

Abstract (Russian)

Разработаны методики синтеза анионных комплексов Cu(I) с клозо-декаборатным анионом, позволяющие получать координационные соединения с широким спектром органических катионов. Показано, что наиболее эффективным методом синтеза, характеризующимся высоким выходом и качеством получаемых продуктов, является реакция взаимодействия ониевых клозо-декаборатов с [Cu2B10H10] в ацетонитриле, подкисленном безводной трифторуксусной кислотой. Методом рентгеноструктурного анализа установлено строение координационного соединения {(C2H5)3NH[CuB10H10]}

Additional details

Additional titles

Original title (Russian)
Анионные комплексы Cу(И) с клозо-декаборатным анионом

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
53
Journal Issue
2
Journal Page Range
p. 238-242
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
39119770
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMINES; BOND ANGLE; BOND LENGTHS; BOROHYDRIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; COPPER COMPLEXES; INFRARED SPECTRA; LATTICE PARAMETERS; MONOCLINIC LATTICES; ORGANIC ARSENIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS
Descriptors DEC
BORON COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIMENSIONS; HYDROGEN COMPOUNDS; LENGTH; ORGANIC COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS

Optional Information

Notes
5 refs., 2 figs., 4 tabs.