Published January 1996 | Version v1
Journal article Metadata-only

Crystal and molecular structures of triphenyl- and trimethyltin 4-nitrothiophenolates

Creators

  • 1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813 (Russian Federation)
  • 2. Nizhnii Novgorod State University, Nizhnii Novgorod (Russian Federation)
  • 3. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333 (Russian Federation)

Description

The x-ray crystal structures of triphenyltin (I) and trimethyltin (II) 4-nitrothiophenolates are reported. Crystals of I and II are monoclinic. For I, a=14.332(3), b=7.765(6), and c=20.724(8) A; β=109.22(3) deg.; Z=4; sp. gr. P21/c; and R=0.037 for 2568 reflections. For II, a=19.032(5), b=7.105(7), and c=20.096(5) A; β=113.43(2) deg.; Z=8; sp. gr. P21/c; and R=0.042 for 2416 reflections. The structure of I is built by discrete molecules, whereas in the structure of II, secondary Sn--O bonds (3.17 and 3.45 A) link molecules into infinite chains. Comparison of geometric parameters of I and II indicates a noticeable contribution of a quinoid form into the structure of II

Additional details

Identifiers

URL
https://www.pleiades.online/contents/cryst/cryst1_96v41cont.htm;

Publishing Information

Journal Title
Crystallography Reports
Journal Volume
41
Journal Issue
1
Journal Page Range
p. 63-70
ISSN
1063-7745
CODEN
CYSTE3

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
35073643
Subject category
S36: MATERIALS SCIENCE; S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Translation
Descriptors DEI
ALKANES; AROMATICS; CRYSTALS; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; ORGANOMETALLIC COMPOUNDS; PHENOLATES; REFLECTION; SPACE GROUPS; TIN COMPOUNDS; X-RAY DIFFRACTION
Descriptors DEC
COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; HYDROCARBONS; ORGANIC COMPOUNDS; SCATTERING; SYMMETRY GROUPS

Optional Information

Notes
Translated from Kristallografiya, ISSN 0023-4761, 41, 70-77 (January-February 1996); (c) 1996 MAIK/Interperiodika