Published August 1999 | Version v1
Journal article

Resonant Ion Pair Formation in Electron Collisions with Ground State Molecular Ions

  • 1. JILA and Department of Physics, University of Colorado and National Institute of Standards and Technology, Boulder, Colorado 80309-0440 (United States)
  • 2. Department of Molecular Physics, Stockholm University, Box 6730 S-113 85 Stockholm (Sweden)
  • 3. Universite Catholique de Louvain, Institut de Physique, Chemin du cyclotron, 2-B1348 Louvain-la-Neuve (Belgium)
  • 4. Manne Siegbahn Laboratory, S-104 05 Stockholm (Sweden)

Description

Resonant ion pair formation from collisions of electrons with ground state diatomic molecular ions has been observed and absolute cross sections measured. The cross section for HD+ is characterized by an abrupt threshold at 1.9thinspthinspeV and 14 resolved peaks in the range of energies 0≤E≤14 eV . The dominant mechanism responsible for the structures appears to be resonant capture and stabilization, modified by two-channel quantum interference. Data on HF+ show structure correlated with photoionization of HF and with dissociative recombination of electrons with this ion. copyright 1999 The American Physical Society

Additional details

Publishing Information

Journal Title
Physical Review Letters
Journal Volume
83
Journal Issue
5
Journal Page Range
p. 951-954
ISSN
0031-9007
CODEN
PRLTAO