Published October 15, 1974
| Version v1
Journal article
Semiclassical treatment of bound state systems. III. A uniform stationary phase integration for the multidimensional problem
Description
The semiclassical bound state formalism is extended to the multidimensional problem by deriving an expression for the reduced density matrix which remains finite when the charge density is calculated. We derive a uniform stationary phase integration technique by mapping the phase of the semiclassical propagator onto a function which has the same behavior as the phase of the free particle propagator, enabling us to incorporate the singularity at t = 0 into the integration. The resulting rdm has the oscillatory behavior of a Bessel function of order d/2, where d is the dimensionality, rather than that of a simple trigonometric function.
Additional details
Identifiers
- DOI
- 10.1063/1.1682508;
Publishing Information
- Journal Title
- The Journal of Chemical Physics
- Journal Volume
- 61
- Journal Issue
- 8
- Series
- J. Chem. Phys.
- Journal Page Range
- 3417-3421
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 6172107
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- BOUND STATE; COLLISIONS; DENSITY MATRIX; FUNCTIONS; PROPAGATOR; SEMICLASSICAL APPROXIMATION; SINGULARITY
- Descriptors DEC
- MATRICES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent