Published October 15, 1974 | Version v1
Journal article

Semiclassical treatment of bound state systems. III. A uniform stationary phase integration for the multidimensional problem

  • 1. Univ. of Chicago

Description

The semiclassical bound state formalism is extended to the multidimensional problem by deriving an expression for the reduced density matrix which remains finite when the charge density is calculated. We derive a uniform stationary phase integration technique by mapping the phase of the semiclassical propagator onto a function which has the same behavior as the phase of the free particle propagator, enabling us to incorporate the singularity at t = 0 into the integration. The resulting rdm has the oscillatory behavior of a Bessel function of order d/2, where d is the dimensionality, rather than that of a simple trigonometric function.

Additional details

Identifiers

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
61
Journal Issue
8
Series
J. Chem. Phys.
Journal Page Range
3417-3421
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
6172107
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
BOUND STATE; COLLISIONS; DENSITY MATRIX; FUNCTIONS; PROPAGATOR; SEMICLASSICAL APPROXIMATION; SINGULARITY
Descriptors DEC
MATRICES

Optional Information

Notes
Updated automatically by Metadata and Full-Text Enrichment Agent