Published May 2009 | Version v1
Journal article

Vibrational modes of hydrogen in (NH4)H5(PO4)2 (Neutron scattering and simulation)

  • 1. Joint Institute for Nuclear Research (Russian Federation)
  • 2. Institut Laue-Langevin (France)
  • 3. Moscow State University (Russian Federation)

Description

The vibrational modes of hydrogen in (NH4)H5(PO4)2 have been investigated by inelastic incoherent neutron scattering at temperatures above (220 K) and below (160 and 5 K) the phase-transition point Tc = 180 K. Computer simulation of vibrational modes has been performed for the low-temperature phase (NH4)H5(PO4)2 at 5 K. The calculated generalized incoherent dynamic factor and the partial incoherent dynamic factors for all hydrogens make it possible to identify the observed modes from acid hydrogens and hydrogens of ammonium ions.

Additional details

Identifiers

Publishing Information

Journal Title
Crystallography Reports
Journal Volume
54
Journal Issue
3
Journal Page Range
p. 477-482
ISSN
1063-7745
CODEN
CYSTE3

Optional Information

Copyright
Copyright (c) 2009 Pleiades Publishing, Ltd.