Published December 22, 1983
| Version v1
Journal article
Kinetics of free radical decay in irradiated L-leucine
Description
The kinetics of the decay of the free radicals produced in crystalline L-leucine by γ-irradiation at 77 K have been studied at temperatures form 50 to 900C. In the first few minutes of the decay some of the ESR spectral peaks increase in intensity while the total moment of the spectra decreases. Hydrogen gas significantly increases the rate of decay while argon seems to decrease it slightly. The decay data can be accurately interpreted in terms of the diffusion-controlled second-order rate equation of Waite
Additional details
Additional titles
- Augmented title (English)
- #gamma# rays
Publishing Information
- Journal Title
- J. Phys. Chem.
- Journal Volume
- 87
- Journal Issue
- 26
- Series
- J. Phys. Chem.
- Journal Page Range
- 5430-5434
- ISSN
- 0022-3654
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 16012962
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ABSORPTION SPECTRA; ADDITIVES; ARGON; CHEMICAL REACTION KINETICS; DECAY; ELECTRON SPIN RESONANCE; EXPERIMENTAL DATA; GAMMA RADIATION; HYDROGEN; LEUCINE; LOW TEMPERATURE; MEDIUM TEMPERATURE; RADICALS; RADIOLYSIS; SAMPLE PREPARATION; TEMPERATURE DEPENDENCE; TIME DEPENDENCE
- Descriptors DEC
- AMINO ACIDS; CARBOXYLIC ACIDS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DATA; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ELEMENTS; INFORMATION; IONIZING RADIATIONS; KINETICS; MAGNETIC RESONANCE; NONMETALS; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; RARE GASES; REACTION KINETICS; RESONANCE; SPECTRA