Published February 1991 | Version v1
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On the ionic equilibrium between complexes in molten fluoroaluminates

Creators

Description

We discuss theoretically (i) the effect of the alkali cation species on the ionic equilibrium between (AlF6)3- and (AlF4)- complexes in molten alkali fluoroaluminates, and (ii) the possible presence of (AlF5)2 - complexes in molten cryolite, in relation to very recent Raman scattering experiments by Gilbert and Materne. (author). 7 refs, 2 tabs

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Additional details

Publishing Information

Imprint Pagination
9 p.
Report number
IC--91/27

INIS

Country of Publication
International Atomic Energy Agency (IAEA)
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
22068409
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S36: MATERIALS SCIENCE;
Descriptors DEI
ALUMINATES; LITHIUM FLUORIDES; MOLTEN SALTS; POTASSIUM FLUORIDES; SODIUM FLUORIDES; THERMODYNAMIC PROPERTIES
Descriptors DEC
ALKALI METAL COMPOUNDS; ALUMINIUM COMPOUNDS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; LITHIUM COMPOUNDS; LITHIUM HALIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; POTASSIUM COMPOUNDS; SALTS; SODIUM COMPOUNDS