Published 1979
| Version v1
Journal article
Solvents as proton carriers. Part 1. Kinetics of isotopic exchange between acetylacetone and Me(acac)3 in DMSO and in DMSO+CH2ClCOOH
Description
Kinetics of isotopic exchange in the systems:. Me(acac)3-14C-Hacac-DMSO, where Me = Cr3+, Co3+ and the effect of hydrogen ions on the rate of ligand exchange in the systems: Me(acac)3-14C-Hacac-solvent-CH2ClCOOH, where solvent=dioxane, DMSO was investigated. (author)
Additional details
Publishing Information
- Journal Title
- Pol. J. Chem.
- Journal Volume
- 53
- Journal Issue
- 7-8
- Series
- Pol. J. Chem.
- Journal Page Range
- 1425-1435
- ISSN
- 0137-5083
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 13663868
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ACETIC ACID; ACETYLACETONE; CARBON 14 COMPOUNDS; CHEMICAL REACTION KINETICS; CHROMIUM COMPLEXES; COBALT COMPLEXES; CONFIGURATION INTERACTION; DISSOCIATION; DMSO; IONS; ISOTOPIC EXCHANGE; LIGANDS; MOLECULAR STRUCTURE; NONAQUEOUS SOLVENTS; ORGANIC CHLORINE COMPOUNDS
- Descriptors DEC
- CARBON COMPOUNDS; CARBOXYLIC ACIDS; CHARGED PARTICLES; CHELATING AGENTS; COMPLEXES; KETONES; KINETICS; MONOCARBOXYLIC ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; REACTION KINETICS; REAGENTS; SOLVENTS; SULFOXIDES; TRANSITION ELEMENT COMPLEXES